Are there any methods that can be used to give a 100% picture of the status. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. It can also be utilized in chloride or fluoride free caustic solutions at moderate temperatures. Caustic may crack carbon as well as stainless steel.
The stress may be applied, as in a pressure system, or it may be residual arising from cold working operations or welding. Stainless steels are more resistant to general corrosion compared with carbon steel. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Results for the polythionic acid test have not been correlated exactly with those of intergranular corrosion tests. Alloy 347 stainless steel plate resists polythionic acid stress corrosion cracking in hydrocarbon service. Cracking of sensitized stainless steels inspectioneering. Stresscorrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Polythionic acid stress corrosion cracking deterioration. If the austenitic stainless steel tubes have become sensitised and need to be mechanically pigged to remove coke andor internal sulphide scale, they should be washed with soda ash solution first. Failure is accelerated by the presence of increasing amounts of intergranular precipitate.
Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to. Astm g35 982015 standard practice for determining the. Austenitic stainless steels are widely used in hydroprocessing units. Effect of polythionic acid concentration on stress. Results show that alloys 304 and 304l, in the solution. This failure mechanism is possible from both inside and outside of a tube. The cracking was found when rust stainingleaks were observed. Other forms of scc in stainless steels include caustic cracking and polythionic acid scc. The test solution was prepared by passing sulfur dioxide gas into deionized water for 4 hours and then bubbling hydrogen sulfide for 3 hours. This acid can cause intergranular corrosion and cracking of austenitic stainless steel vessels or of the cladding on carbon steel and lowalloy steel vessels, especially in heat affected zones that are sensitized by welding.
Among them, the scc due to polythionic acid h 2sxo 6, x 3 6 is one of the most serious corrosion issue affecting equipment for hydrotreater and hydrocracker in complex refinery. Standard recommended practice austenitic stainless steels. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking. An electrochemical study on stress corrosion cracking of. The cast stainless generally did not polythionic crack but, the ferrite content were susceptible to sigma phase embrittlement.
The applications for stainless steels in petroleum refining are many and varied. Duplex stainless steel is a practical solution to most 304l or 316l scc failures. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steels, such as alloy 304. Polythionic stress corrosion cracking of stainless steel tube environment. This acidic condition, along with temperatures high enough to sensitize stainless steel, often led to polythionic acid stress corrosion cracking of the valve bodies. The item was exposed to sulfur containing natural gas in a continuous flare.
Abstractlow temperature stress corrosion cracking of. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Development of fitforpurpose austenitic stainless steels. Introduction the 304 stainless steel charge heater coil of a naphtha hydrotreater unit nht was found to be extensively cracked following unit shutdown, when soda ash washing was applied. Exposure of nonstabilized austenitic stainless steel to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. Stress corrosion cracking by krittin rattakham youtube. Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. Resistance to corrosion stainless steel tubing manufacturer. Rp0170hd1985sg protection of austenitic stainless steel from polythionic acid stress corrosion cracking during shutdown of refinery equipmenthd1985 available for download methods to protect austenitic stainless steel from polythionic acid stress corrosion cracking scc found to occur during downtimes and contiguous shutdown and startup. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. Chemical studies of polythionic acid stresscorrosion cracking.
Electrochemical characteristics of polythionic acid stress corrosion cracking have been examined mainly on sensitized type 304 stainless steel. Alloy 347 stainless steel plate does not perform well in chloride solutions, even in small concentrations, or in sulfuric acid. In the process units with polythionic acid stress corrosion cracking ptascc such as hydrotreater or hydrocracker, the neutralization treatment like soda ash washing andor pwht, post weld heat treatment, are conducted for stabilized austenitic stainless steels of tp321h or tp347h to mitigate the potential of ptascc. Polythionic acid stress corrosion cracking of type 310 stainless steel. A hydrotest at 735 psi revealed numerous leaks in four tubes from a heater. Examples of polythionic acid scc pascc in a sensitized austenitic stainless steel and caustic scc in carbon steel equipment are presented. Howe, effects of welding and thermal stabilization on the sensitization and polythionic acid stress corrosion cracking of heat and corrosion resistant alloys, paper no. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainless steel tube materials after exposures to temperatures in excess of 700f to.
For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. Stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0. Experience with polythionic acid stress corrosion cracking in reactor 0707 petroleum 14 feb 07 10. The most commonly available duplex in north america is 2205, at a cost roughly 20% above that of 316l. Stresscorrosion cracking of sensitized type 304 stainless. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail.
Polythionic acid is formed in the presence of sulfur, moisture and oxygen. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment view abstract product details detail summary. The purpose of this booklet, therefore, is to help materials engineers identify those applications and to provide data to support the use of stainless steels in the hightemperature, corrosive environments that may be encountered. Stress corrosion cracking issues in syngas plants that may. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. In certain process units, such as hydrocracking, soda ash washing neutralization of austenitic stainless steel is required during turnarounds to mitigate the potential for polythionic acid stress corrosion cracking pta scc. Stress corrosion cracking susceptibility of stainless. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx. Polythionic acid stress corrosion cracking in heater pipes. Chloride stress corrosion cracking of an austenitic.
This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. The coil carries sour naphtha 350 ppmw s feed and hydrogen. The ptascc of stainless steels is generally caused by. They can be subject to polythionic acid stress corrosion cracking during shut down.
Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in order to identify the mode of failure. What are the industrial practices being followed in. Experience with polythionic acid stress corrosion cracking. Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Alloy for resistance to polythionic acid stress corrosion. Polythionic stress corrosion cracking of stainless steel tube. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby. Results reveal that the stress corrosion life decreases rapidly on increasing the concentration from 0. Sulfur can come from feed stock, additives or fuels. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking.
Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. In this chapter, the conditions for the occurrence of scc are first introduced. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. Pdf polythionic acid corrosion in refinery hydroprocessors. Alloy 347347h heat resistant stainless steel plate. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. Polythionic acid stress corrosion cracking stainless.
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